Oxidation-sulfidation behavior of Ni aluminide in oxygen-sulfur mixed-gas atmospheres

Oxidation-sulfidation studies were conducted on sheet samples of nickel aluminide, containing 23.5 at. % Al, 0.5 at. % Hf, and 0.2 at. % B in an annealed condition and after preoxidation treatments. Continuous weight-change measurements were made by a thermogravimetric technique in exposure atmospheres of air, a low- gas mixture, and low- gas mixtures with several levels of sulfur. Detailed scanning electron microscopy (SEM), X-ray, and electron microprobe analyses of the corrosion product scale layers were performed. The air-exposed specimens developed predominantly nickel oxide; the specimen exposed to a low- .     

High-rate capability of spinel LiNi0.05Mn1.95O4 cathode for Li-ion batteries prepared via coprecipitated precursor

Spinel LiNi0.05Mn1.95O4 cathode material for lithium ion batteries was synthesized by solid-state reaction from coprecipitated Ni-Mn hydroxide precursors and characterized by X-ray diffraction（XRD）, scanning electron microscopy（SEM） and galvanostatic charge-discharge tests. It is found that LiNi0.05Mn1.95O4 powder has an ordered cubic spinel phase （space group Fd3m） and exhibits superior rate capability. After 450 cycles, the LiNi0.05Mn1.95O4/carbonaceous mesophase spheres（CMS） Li-ion batteries can retain 96.0% and 93.3% capacity at 5C and 10C charge/discharge rate, respectively, compared with 85.3% （5C） and 80.5% （10C） retention for LiMn204 batteries. However, the initial discharge capacity of LiNi0.05Mn1.95O4/CMS batteries at 1C charge/discharge rate （96.20 mA.h/g） is slightly lower than that of the LiMn2O4 batteries （100.98 mA.h/g） due to the increased average oxidation state of Mn inLiNi0.05Mn1.95O4.     

直齿轮精密塑性成形时齿面裂纹的产生机理及控制方法

本文通过对内齿轮缩挤成形工艺的有限元模拟 ,分析了直齿轮成形时齿面裂纹的产生机理 ,并从理论上进行了解释 ,进而提出了防止齿面裂纹产生的方法     

Formation and crystallization of bulk Pd_(82)Si_(18) amorphous alloys

1　INTRODUCTIONMetallicglassisregardedasastatethatisofdis orderunlikecrystalalloyswith periodicatomstruc ture.Soitshowsexcellentcapabilitiesofsoftmag netism ,mechanics ,corrosionresistance ,etc .How ever ,mostofamorphousalloyswereproducedbyus ingrapidsolidificationmethodssuchassplatquench ing ,meltspinning ,andsoon ,withcharacteristiccoolingratesof 10 4 10 6 K/s .Becauseamorphousal loysarepreparedwithsilk ,powderandribbon ,itisgreatlylimitedinengineeringapplication .Recently ,severalbulk…     

残余奥氏体对20Mn2SiVB钢的疲劳裂纹扩展的影响

研究了残余奥氏体对20Mn2SiVB钢疲劳裂纹扩展的影响。结果表明,在贝氏体铁索体中有残余奥氏体膜的存在,残余奥氏体膜可起到提高断裂韧性的作用;在应力强度因子较高的范围内,疲劳裂纹扩展速率受钢的断裂韧性影响,断裂韧性高,裂纹扩展速率低。     

Microstructure and tensile properties of magnesium alloy modified by Si/Ca based refiner

Microstructure and mechanical properties of pure magnesium and AZ31 alloy with Ca/Si based refiner addition were investigated. The results indicate that addition of Ca/Si based refiners to pure magnesium and AZ31 alloy results in remarkable microstructure refinement. With proper amount of refiner addition, the grain size in as cast ingots can be one order of magnitude lower than that without refiner addition. Small amount of refiner addition to AZ31 alloy increases both ultimate strength and yield strength significantly,while the ductility of the alloy with refiner addition is similar to that without refiner addition. Addition of refiner improves the deformability of AZ31 alloy and extruded or hot rolled specimens （rods or sheets） with refiner addition exhibit higher surface quality and mechanical properties than those without refiner addition.     

Liquid Impact Based Material Micro-Forming Technology

The objective of this study was to investigate material deformation in the course of a high-speed (>1500 m/s) water impact and to use the acquired knowledge for improvement of the forming technology. An experimental setup for projectile fabrication was constructed and a series of experiments involving sub-millimeter and micron scale metal deformation was performed. The geometry and topography of the generated samples were investigated using advanced surface examination techniques and the feasibility of the liquid impact based micro-forming technology was demonstrated. This article was presented at Materials Science & Technology 2006, Innovations in Metal Forming symposium held in Cincinnati, OH, October 15-19, 2006.     

铝合金VP PMIG焊电弧过零稳定性

在薄板铝合金变极性脉冲熔化极惰性气体保护焊中,采用全桥高压脉冲双向稳弧方式,研究了高压稳弧脉冲电压幅值、脉冲持续时间、脉冲触发时刻、基值电流对焊接电流过零稳定性的影响.在小基值电流过零时,稳弧脉冲电压比基值电流对焊接电流过零稳定性的影响大.焊接电流过零的稳定性与稳弧脉冲电压的上升率有关,稳弧脉冲电压上升率有一个临界区间,使焊接电流过零时不稳定,采用稳弧脉冲电压上升率判断焊接电流过零稳定性,能够为铝合金VP PMIG焊焊接电流过零再引燃提供有效、可靠的依据.     

Design of Bulk metallic glasses with high glass forming ability and enhancement of plasticity in metallic glass matrix composites: A review

To overcome some of the limits of existing metallic alloys, a new alloy design concept has been introduced recently in order to control the crystallinity, i.e. to utilize crystalline, quasicrystalline, and amorphous structures. In particular, bulk metallic glasses (BMGs) receive great attention because of their unique properties due to their different atomic configuration. Recently, significant progress in enhancing glass forming ability (GFA) has led to the fabrication of BMGs having potential for application as structural and functional materials. Moreover, successful design of BMG matrix composite microstructure suggests that the plasticity of BMGs can be controlled properly. In this review article, we introduce recent research results on the design of BMGs with high GFA and on the enhancement of plasticity in metallic glass matrix composites.     

半固态A356铝合金流变特性研究

用自行研制的同轴圆柱旋转流变仪对半固态A356铝合金浆料的流变特性及组织演变进行研究.结果表明:等温剪切时,浆料稳态表观粘度随着剪切速率的增大而下降,半固态A356铝合金具有明显的触变性.在连续冷却条件下,半固态浆料的表观粘度随着温度的降低而先缓慢后迅速增大,冷却速度显著影响半固态A356铝合金的表观粘度,降低冷却速度,由于搅拌充分而导致表观粘度明显下降.显微结构分析也可以反映出剪切速率、温度和冷却速度对表观粘度的影响规律.